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杨高升

作者: 杨高升     发布时间: 2020-01-19 点击数:

     
       
 

杨高升  教(jiao)授、博士生导师

   邮(you)箱: gshyang@littlemommynest.com          电话(hua):  13955391536

   实(shi)验室(shi): 1007-1008 (礼勤楼)            办公室: 1119 (礼(li)勤楼)

   ORCID:  http://orcid.org/0000-0002-7891-3972

 

所受教育

        1981年(nian)9月(yue)–1985年(nian)7月(yue)  安徽师(shi)范(fan)大学(xue)化学(xue)系学(xue)习,获(huo)学(xue)士学(xue)位 

        1988年(nian)9月(yue)–1991年(nian)7月(yue)  安(an)徽师范大学(xue)有机化学(xue)研(yan)究(jiu)所硕士研(yan)究(jiu)生(sheng),获理学(xue)硕士学(xue)位(wei)

        2002年(nian)9月(yue)–2005年(nian)6月(yue)  南京大学化学化工(gong)学院博士(shi)研究生,获理学博士(shi)学位 

 职(zhi)称职(zhi)位 

        1985年7月(yue)–现在  安徽师范大学助教(jiao),讲师,副教(jiao)授,教(jiao)授 (2005年) 

        2004年6月–现在  安徽师范(fan)大学硕士(shi)生导师 

        2012年7月–现在  安(an)徽师范大学(xue)博士生(sheng)导师 

 主持项目

        1. “稀土有机(ji)化合物催化不饱(bao)和键(jian)对氮氢键(jian)的不对称(cheng)串联插(cha)入反应”,国家自(zi)然科学基金面上(shang)项(xiang)目,直接(jie)经费65万元,2017年1月(yue)–2020年12月(yue),项(xiang)目负责人 (21672005)

        2. “多取代D–A型环丙烷与芳香醛(quan)的[3+2]环加成反应及其在呋喃木酚素合成中的应用”,国家自然科学基金面(mian)上项目,60万(wan)元,2012年1月–2015年12月,项目负责(ze)人 (21172002) 

        3. “新型(xing)二胺稀土(tu)配(pei)合物的合成及其催化烯(xi)烃氢(qing)胺化反(fan)应研究(jiu)”,国家自然科(ke)学基金面(mian)上项(xiang)目(mu),37万(wan)元(yuan),2010年1月(yue)–2012年12月(yue),项(xiang)目(mu)负责人(ren) (20972001) 

        4. “手(shou)性胺–硫脲催化的不对称多(duo)组分反(fan)应研究(jiu)”,安(an)徽省自然科学(xue)基金面(mian)上项(xiang)目,5万元,2009年1月(yue)–2011年12月(yue),项(xiang)目负(fu)责人 (090416236) 

 研(yan)究领域(yu)

        1. 金(jin)属有机化学 

        2. 有机合(he)成化学 

        3. 不对称催化 

 讲授课程(cheng)

        1. 有机化学-I(本科)

        2. 有机化学-II(本科)

        3. 有机波谱分析(本科)

        4. 有机合成化学(本科)

        5. 有机波谱学(硕士)

 获奖情况

        1. 安徽省“教学名师”(2015年)

        2. 安徽师范大学“教学名师”(2013年)

        3. 安徽师范大学优秀教学奖特等奖 (2011年)

        4. 安徽师范大学“三育人”先进工作者 (2007年)

        5. 安徽师范大学“皖泰”教师教学优秀奖一等奖 (2001年)

 研究进展(zhan)

2130A

                                                                                                                           

 

2871A

1AE4E

1FC52

 

  代表性论文

      30. Peiying Su, Huimin Li, Wenlong Chen, Gen Luo, Gaosheng Yang* and Zhuo Chai, “Lewis Acid Catalyzed [3+2] Annulations of γ-Butyrolactam-Fused Donor–Acceptor Cyclopropanes with Aromatic Aldehydes and Aldimines”, Eur. J. Org. Chem. 2020, 5380–5387. 

      29. Xingyu Zhang, Manli Feng, Gaosheng Yang* and Zhuo Chai, “Sc(OTf)3-Catalyzed Chemodivergent Annulations of γ-Butyrolactone-Fused Cyclopropanes with Anthranils”, J. Org. Chem. 2020, 85, 430–440.

      28. Yue Shen, Jun Chai, Gaosheng Yang*, Wenlong Chen and Zhuo Chai, “Stereocontrolled Synthesis of trans/cis-2,3-Disubstituted Cyclopropane 1,1-Diesters and Applications in the Syntheses of Furanolignans”, J. Org. Chem. 2018, 83, 12549–12558.

      27. Pengfei Yang, Yue Shen, Manli Feng, Gaosheng Yang* and Zhuo Chai, “Lewis Acid Catalyzed [3+2] Annulation of γ-Butyrolactone Fused Cyclopropane with Aldehydes/Ketones”, Eur. J. Org. Chem. 2018, 4103–4112. 

      26. Yue Shen, Pengfei Yang, Gaosheng Yang*, Wenlong Chen, Zhuo Chai, “Lewis acid-catalyzed enantiospecific [3 + 2] annulations of γ-butyrolactone fused cyclopropanes with aromatic aldehydes: synthesis of chiral furanolignans”, Org. Biomol. Chem. 2018, 16, 2688–2696.

      25. Manli Feng, Pengfei Yang, Gaosheng Yang*, Wenlong Chen, Zhuo Chai, “FeCl3-Promoted [3 + 2] Annulations of γ-Butyrolactone Fused Cyclopropanes with Heterocumulenes”, J. Org. Chem. 2018, 83, 174–184.

      24. Zhuo Chai, Yemei Wang, Mujun Tang, Xiaolong Mu, Jinsong Hou, Gaosheng Yang*, “Chiral rare-earth metal complexes with a tridentate amido-fluorenyl ligand: Syntheses, structures and catalytic performance”, J. Organomet. Chem. 2017, 846, 236–241.

      23. Zhuo Chai, Jiang Chu, Yunyi Qi, Mujun Tang, Jinsong Hou and Gaosheng Yang*, “Half-sandwich chiral rare-earth metal complexes with linked tridentate amido-indenyl ligand: synthesis, characterization, and catalytic properties for intramolecular hydroamination”, RSC Adv. 2017, 7, 1759–1765.

      22. Deju Hua, Pengfei Yang, Yue Shen, Gaosheng Yang*, Zhuo Chai*, “PCl5-mediated ring-openings of trans-2,3-disubstituted cyclopropane-1,1-diesters: A stereoselective way to trisubstituted vinyl chlorides”, Tetrahedron 2017, 73, 1205–1210.

      21. Gaosheng Yang*, Tingting Wang, Jun Chai, and Zhuo Chai*, “AlCl3-Catalyzed [3+2] Annulations of cis-2,3-Disubstituted Cyclopropane 1,1-Diesters with Cyclic Ketones: Diastereoselective Construction of Spirotetrahydrofurans”, Eur. J. Org. Chem. 2015, 1040–1046.

      20. Zhuo Chai, Dezhi Hua, Kui Li, Shuangliu Zhou, Jiang Chu, Gaosheng Yang*, “Rare-earth metal complexes with tridentate linked amido-indenyl ligand: Synthesis, characterization, and catalytic properties for intramolecular hydroamination”, J. Organomet. Chem. 2014, 768, 136–139.

      19. Zhuo Chai, Dezhi Hua, Kui Li, Jiang Chu and Gaosheng Yang*, “A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination”, Chem. Commun. 2014, 50, 177–179.

      18. Gaosheng Yang*, Yongxian Sun, Yue Shen, Zhuo Chai*, Shuangliu Zhou, Jiang Chu, and Jun Chai, “cis-2,3-Disubstituted Cyclopropane 1,1-Diesters in [3 + 2] Annulations with Aldehydes: Highly Diastereoselective Construction of Densely Substituted Tetrahydrofurans”, J. Org. Chem. 2013, 78, 5393–5400.

      17. Yongxian Sun, Gaosheng Yang*, Zhuo Chai*, Xiaolong Mu and Jun Chai, “AlCl3-promoted [3 + 2] annulation of cis-2,3-disubstituted cyclopropane 1,1-diesters with isothiocyanates: stereoselective synthesis of densely substituted 2-iminodihydrothiophenes”, Org. Biomol. Chem. 2013, 11, 7859–7868.

      16. Yongxian Sun, Gaosheng Yang*, Yue Shen, Zan Hua, Zhuo Chai*, “Stereoselective cyclopropanation of a-bromochalcone with diethyl malonate promoted by K2CO3”, Tetrahedron 2013, 69, 2733–2739.

      15. Gaosheng Yang*, Chongrong Luo, Xiaolong Mu, Tingting Wang and Xin-Yuan Liu*, “Highly Efficient Enantioselective Three-Component Synthesis of 2-Amino-4H-Chromenes Catalysed by Chiral Tertiary Amine-Thioureas”, Chem. Commun. 2012, 48, 5880–5882.

      14. Gaosheng Yang*, Yue Shen, Kui Li, Yongxian Sun, Yuanyuan Hua, “AlCl3-Promoted Highly Regio- and Diastereoselective [3+2]Cycloadditions of Activated Cyclopropanes and Aromatic Aldehydes: Construction of 2,5-Diaryl-3,3,4-trisubstituted Tetrahydrofurans”, J. Org. Chem. 2011, 76, 229–233. (This work has been highlighted in Synfacts)

      13. 骆崇荣, 陈楠楠, 华德智, 杨高升*, 苯磺酰硫脲衍生物的无溶剂合成,有机化学, 2011, 31, 2167–2172.

      12. Gaosheng Yang*, Yuanyuan Hua, Yue Shen, “K2CO3-Promoted Cascade Michael-Alkylation Reactions: A Facile Preparation of Diethyl trans-2,3-Disubstituted 1,1-Cyclopropanedicarboxylates”, Chin. J. Chem. 2009, 27, 1811–1819.

      11. Xiaosheng Wang, Changwu Zheng, Shengli Zhao, Zhuo Chai, Gang Zhao*, Gaosheng Yang*, “Organocatalyzed Friedel–Craft-type reaction of 2-naphthol with β,γ-unsaturated a-keto ester to form novel optically active naphthopyran derivatives”, Tetrahedron: Asymmetry 2008, 19, 2699–2704.

      10. Xiaosheng Wang, Gaosheng Yang*, and Gang Zhao*, “Enantioselective synthesis of naphthopyran derivatives catalyzed by bifunctional thiourea-tertiary   amines”, Tetrahedron: Asymmetry 2008, 19, 709–714.

        9. 吴红伟, 杨高升*, a-卤代酮(tong)与芳(fang)香二胺经氧化–缩合过程一锅法合成喹喔啉衍生物,有(you)机化(hua)学(xue), 2008, 28, 2132–2136.

        8. Gaosheng Yang, Huiwei Tang, Yizhi Li, Jing Hong, Zijian Guo, Longgen Zhu*, “Syntheses, structures, and properties of two dinuclear palladium (II) complexes of a single macrocyclic hexaaza ligand with two hydroxyethyl pendants”, Inorg. Chem. Commun. 2005, 8, 862–865.

        7. Gaosheng Yang, Ren Miao, Yizhi LI, Chen Jin, Jin Hong, Zijian Guo, Longgen Zhu*, “Self-inclusion of a New Calix[4]arene Derivative via Associated Acetonitrile: X-ray Diffraction and Density Functional Theory Studies”, Chin. J. Chem. 2005, 23, 852–856.

        6. Gaosheng Yang, Ren Miao, Yizhi Li, Jing Hong, Chuenmei Zhao, Zijian Guo and Longgen Zhu*, “Synergic effect of two metal centers in catalytic hydrolysis of methionine-containing peptides promoted by dinuclear palladium(II) hexaazacyclooctadecane complex”, Dalton Trans. 2005, 1613–1619.

        5. Gaosheng Yang, Ren Miao, Chen Jin, Yuhua Mei, Huiwei Tang, Jin Hong, Zijian Guo and Longgen Zhu*, “Determination of binding sites in carboplatin-bound cytochrome c using electrospray ionization mass spectrometry and tandem mass spectrometry”, J. Mass Spectrom. 2005, 40, 1005–1016.

        4. Gaosheng Yang, Chen Jin, Yizhi Li, Jing Hong, Ren Miao, Chuenmei Zhao, Zijian Guo and Longgen Zhu*, “Conformations and Structures of Two Novel Upper Rim Disubstituted Derivatives of Tetra-O-alkylcalix[4]arene: The Effect of Substituents”, J. Incl. Phenom. Macrocycl. Chem. 2005, 52, 119–127.

        3. Gaosheng Yang, Chen Jin, Jing Hong, Zijian Guo, Longgen Zhu*, “Ab initio and density functional theory studies on vibrational spectra of palladium (II) and platinum (II) complexes of methionine and histidine: effect of theoretical methods and basis sets”, Spectrochim. Acta Part A 2004, 60, 3187–3195.

        2. Gaosheng Yang, Jian-Bing Hu, Gang Zhao*, Yu Ding and Min-Hua Tang, “Catalytic enantioselective borane reduction of aromatic ketones with sulfonyl (S)-prolinol”, Tetrahedron: Asymmetry 1999, 10, 4307–4311.

        1. Gaosheng Yang, Xiao-juan Xie, Gang Zhao, Yu Ding*, “Palladium catalyzed cross-coupling reaction of organoboronic acids with β-(perfluoroalkyl)ethyl   iodides”, J. Fluorine Chem. 1999, 98, 159–161.

 会(hui)议论文(wen)

      11. 祁云毅,王(wang)业梅,侯(hou)金松,冯(feng)曼丽,苏培(pei)盈,杨鹏飞(fei),杨高升*, “含(han)手性配位性侧链的单茂稀土金属(shu)有机(ji)化合物的合成、结构及催化性能(neng)”, 第十九届全国(guo)金属(shu)有机(ji)化学(xue)学(xue)术讨论(lun)会, 472, 中国(guo), 杭州, 2016年10月28日(ri)–31日(ri).

      10. 王(wang)业梅,沈(shen)悦,杨鹏(peng)飞(fei),杨高升*, “(1R,2R)-N,N-二(er)甲基(ji)-N'-[2-(9-芴基(ji))乙基(ji)]-1,2-环己二(er)胺稀土配合(he)(he)物的合(he)(he)成(cheng)及其催化性能研究”, 中国化学会第九届有机化学会议, 534, 中国, 长(zhang)春, 2015年7月(yue)28日–31日.

        9. 王(wang)婷婷,柴俊,祁云毅,沐小龙,杨高升*, “AlCl3促进2,3-二取代-1,1-环(huan)丙(bing)烷(wan)二羧酸(suan)二乙酯与C=X键(jian)的(de) [3 + 2] 形式环(huan)加成反应(ying)研究(jiu)”, 第十(shi)八届全(quan)国金(jin)属有机化学学术(shu)讨(tao)论会, 235, 中国, 兰(lan)州(zhou), 2014年8月(yue)19日–22日.

        8. 楚江,王业梅(mei),唐慕君,华徳举,杨高升*, “手(shou)性半夹心稀土金属(shu)有(you)机配合物的合成及(ji)其(qi)催(cui)化(hua)氨基烯烃分子内氢胺(an)化(hua)/环化(hua)反(fan)应(ying)研究”, 第十八届全国金属(shu)有(you)机化(hua)学(xue)学(xue)术讨论会, 236, 中国, 兰州, 2014年8月19日(ri)–22日(ri).

        7. 陈楠楠, 王业梅, 唐幕君(jun), 杨高升*, “二甲基硅基桥联双(N,N-二甲基乙二胺(an))稀土金属配(pei)合(he)物的合(he)成及其催化(hua)芳香醛、酮的氢磷化(hua)反应”, 中国(guo)化(hua)学会第(di)八届(jie)有机化(hua)学会议, 4078, 中国(guo), 重庆, 2013年10月(yue)17日(ri)–20日(ri).

        6. 华(hua)德智, 李奎, 楚江(jiang), 杨(yang)高升(sheng)*, “桥联茚基二(er)胺(an)稀(xi)土(tu)配合物的合成(cheng)及(ji)其催化(hua)烯烃氢(qing)胺(an)化(hua)反应(ying)”, 第十七(qi)届全国(guo)(guo)金属有机化(hua)学学术讨论会, P1-97, 中国(guo)(guo), 北京, 2012年10月19日–22日.

        5. 李奎(kui), 华德(de)智, 楚江, 杨(yang)高升*, “桥联茚基手性二胺稀土配合物的合成及其催化(hua)烯烃(ting)氢胺化(hua)反(fan)应(ying)”, 第十七届全国(guo)(guo)金属有机化(hua)学(xue)学(xue)术讨论会, P1-98, 中国(guo)(guo), 北京(jing), 2012年10月19日(ri)–22日(ri).

        4. 孙永先, 华赞, 杨高升*, “多取代D-A型环丙烷衍生物与碳硫(liu)双键(jian)的[3+2]环加成反应研究(jiu)”, 第十(shi)届(jie)江(jiang)淮有机化学论坛(tan), 58, 中国, 合肥, 2012年11月2日–4日.

        3. 骆崇荣, 王婷婷, 孙永先, 杨高升*, “2-氨基-4H-色烯衍生物的不对(dui)称有(you)机催化(hua)三组分(fen)合(he)成”, 中国(guo)化(hua)学会第(di)七届(jie)有(you)机化(hua)学会议, 1-134, 中国(guo), 南(nan)京, 2011年11月12日–15日. 

        2. 华(hua)德智, 骆崇荣, 李(li)奎, 杨高(gao)升(sheng)*, “手性叔胺–硫(liu)脲催化(hua)不对称(cheng)三组分反应研究”, 中(zhong)国化(hua)学(xue)会(hui)第七届有机(ji)化(hua)学(xue)会(hui)议, 1-135, 中(zhong)国, 南京, 2011年11月12日(ri)(ri)–15日(ri)(ri). 

        1. 沈悦(yue), 吴红伟(wei), 杨(yang)高升*, “DMSO作用下?-溴代苯乙酮与2,3-二氨基(ji)马(ma)来腈的反应研究(jiu)”, 中国化学会第(di)六届有(you)机化学会议(yi), P537(上册), 中国, 西安, 2009年8月17日(ri)–20日(ri). 

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