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胡益民

作者: 胡益民     发布时间: 2019-09-12 点击数:
   

                   

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  Prof. Yimin Hu

 Email:yiminhu@littlemommynest.com 

 

          胡益民,男,博士,二级教授,博士生导师,安徽省学术与技术带头人。1993年本科毕业于安徽师范大学,1997年毕业于安徽师范大学获硕士学位,2003年毕业于南京大学获博士学位。2004年在美国 Bowling Green State University从事博士后研究。发表学科前沿学术性研究论文包括《Angew. Chem. Int. Ed.》、《Chem. Commun.》、《Chem. - Eur. J.》、《Adv. Synth. Catal.》、《J. Org. Chem.》、《Chem. - Asian. J.》等国际著名期刊。参加国际重要学术会议作邀请报告7次,成功申报了国家自然科学基金面上项目5项;曾担任德国《应用化学》审稿人并获得2010年度 “Thieme Chemistry Journals Award”国际奖。讲授课程: 有机化学、有机化学选论、理论有机化学、化学学科进展等。研究工作方向: 着眼于新医药、新材料和新能源的研究,致力于设计新的催化剂、发现新的催化反应。目前主要从事绿色有机合成及过渡金属催化的与药物能源材料相关的分子转化及其过渡金属催化芳香杂环碳氢键活化以及芳炔HDDA的串联环化反应研究。

 

 

 

      主持(chi)项(xiang)目              

1. 多官能化复杂芳(fang)香(xiang)功能化合(he)物(wu)简洁合(he)成(cheng)方法学研究 国家自然科学基金 项目号(hao): 2157200265万,起止(zhi)年月(yue): 2016.01-2019.12, 项目(mu)负(fu)责人

2. 过(guo)渡(du)金属催(cui)化的烯(xi)丙基化及多重烯(xi)炔连续Domino反(fan)应构(gou)建几种环状复杂体系化合物研究 国(guo)家自然科学基金(jin) 项目(mu)号: 2127200580万,起(qi)止年月: 2013.01-2016.12,项目负责(ze)人

3.  PodophyllotoxinConidendrin骨架(jia)及其(qi)衍生物的高效(xiao)合(he)成(cheng)方(fang)法研究 国家自然科学基金 项目(mu)号(hao): 21072003 ; 36.0万(wan); 2011–2013年(nian), 项(xiang)目负责人(ren)。

4.  芳香(xiang)杂(za)环C-H键(jian)活(huo)化构筑多环有机物的Domino反应研究 国(guo)家自然科学基金 项目号(hao): 20872002 ; 35.0万(wan); 2009–2011, 项目负(fu)责人。

5.  钯、铑、镍催化(hua)活性(xing)丙烯酰基在(zai)离子(zi)液(ye)体(ti)中的选择性(xing)成环偶联(lian)反应研究 国家(jia)自(zi)然科学基金(jin) 项目号: 20572001; 16.0万(wan)(含学校(xiao)配套(tao)经费); 2006–2007, 项目负责人(ren)。

6.  安徽省(sheng)高等(deng)学校(xiao)十五优秀人才(cai)计划学(xue)科(ke)带头人基金 3.2万(wan); 2005–2008年(nian), 项目(mu)负责(ze)人。                      

       
       

  发表论文        

1. “One-Step Synthesis of the Benzocyclo[penta- to octa-]isoindole Core”, Yimin Hu*, Chenli Yu, Dong Ren, Qiong Hu, Lidong Zhang, Dong Cheng, Angewandte Chemie International Edition, 2009, 48(30), 5448-5451. Angewandte Chemie, 2009, 120(30), 5556-5559.         

2. "Direct methylation and carbonylation of in situ generated arynes via HDDA-Wittig coupling", Baohua Liu,Chunyan Mao,Qiong Hu,Liangliang Yao,Yimin Hu*, Org. Chem. Front.2019, 6, 2788–2791.

3. "Versatile Dibenzothio[seleno]phenes via Hexadehydro-Diels–Alder Domino Cyclization", Baohua Liu, Qiong Hu, Yinshan Wen, Bo Fang, Xiaoliang Xu, Yimin Hu*, Frontiers in Chemistry,2019,374.

4.Fused Multifunctionalized Dibenzoselenophenes from Tetraynes, Yimin Hu*, Jie Ma, Lidong Li, Qiong HuShuang LvBaohua LiuShaowu Wang*,Chem. Commun. 2017, 53, 1542-1545.        

5. Direct Access to Fused Salicylaldehydes and Salicylketones from Tetraynes, Yimin Hu*Yadong HuQiong HuJie MaShuang LvBaohua LiuShaowu Wang*,Chem. Eur. J. 2017, 23, 4605-4072.        

6. Fused Multifunctionalized Chromenes from Tetraynes and α,β-Unsaturated Aldehydes, Xiangzhen Meng, Shuang Lv, Dong Cheng, Qiong HuJie MaBaohua Liu, Yimin Hu* Chem. Eur. J. 2017, 23, 6264-6271.        

7. Fused Multifunctionalized Isoindole-1,3-diones via the Coupled Oxidation of Imidazoles and Tetraynes, Qiong Hu, Lidong Li, Fei Yin, Hao Zhang, Yadong Hu, Baohua Liu and Yimin Hu* RSC Adv. 2017, 7, 49810-49816.        

8. Synthesis of a Type of Bridged Heterocycles via Tetraynes, Xiangzhen Meng, Dong Cheng*, Shuang Lv, Jie Ma, Yimin Hu* Heterocycles 2017, 94, 2111-2124.        

9. Convenient One-Step Construction of Yne-Functionalized Aryl Halides through Domino Cyclization from Tetraynes, Hao Zhang, Qiong Hu, Lidong Li, Yimin Hu,* Pingping Zhou, Xiaorong Zhang, Haifeng Xie, Shaowu Wang,* Chem. Commun. 2014, (25), 3335-3337.        

10. One-Step Synthesis of Diazaspiro[4.5]decane Scaffolds with Exocyclic Double Bonds, Lidong Li, Qiong Hu, Pingping Zhou, Haifeng Xie, Xiaorong Zhang, Hao Zhang, Yadong Hu, Fei Yin, Yimin Hu,* Org. Biomol. Chem. 2014, 12, 5356-5359.        

11. Domino Access to Yne-functionalized Benzoisoindole from Triynes, Lidong Li, Qiong Hu, Pingping Zhou, Haifeng Xie, Xiaorong Zhang, Hao Zhang, Hua Wang, Yimin Hu,* SYNTHESIS 2014, 46, 1547-1554.        

12. Fused Benzo[b]fluorenols: Palladium-Catalyzed Intramolecular Dehydroaromatization and Carbonyl Reduction, Quansheng Zhao, Qiong Hu, Lei Wen, Min Wu, Yimin Hu*, Adv. Synth. Catal. 2012, 354, 2113-2116.        

13. Synthesis of highly substituted dihydropyrrolophenanthridine derivatives by tandem reaction, Yimin Hu*, Tao Zhu, Xiaolong Mu, Quansheng Zhao, Tao Yu, Lei Wen, Yulong Zhang, MinWu, Hao Zhang, Tetrahedron, 2012, 68, 311-318.        

14. Fused Phenanthridines: Domino Cyclization of 1,6-Diynes with Bromo(iso)quinoline, Yimin Hu*, Yongjie Sun, Jiping Hu, Tao Zhu, Tao YuQuansheng Zhao, Chemistry-Asian Journal, 2011, 6, 797-800.        

15. Construction of 3-Allyliodene-4-vinyltetrahydrofurans and 3-Allylidene-4-vinylpyrrolidines Via Sequential Domino Allylation/Olefination of CC Triple Bonds, Tuan-jie Meng, Yimin Hu*, Quansheng Zhao, Tao Yu, and Shaowu Wang*, Tetrahedron, 2011, 67, 8710-8716.

16 “Efficient Activation of Aromatic C-H Bonds for Fused Polyaromatic Hydrocarbon Construction”, Yimin Hu,* Hao Yao, Yongjie Sun, Jing Wan, Xiangang Lin, Tao Zhu, Chemistry-A European Journal, 201016, 7635-7641.         

17. “Efficient Construction of Tri- and Tetracyclic Heterocycles from Linear 1,6-Dienes by a Domino Reaction”, Yimin Hu,* Fengfa Song, Fenghua Wu, Dong Cheng, and Shaowu Wang*, Chemistry-A European Journal, 200814, 3110-3117.         

18. Rapid construction of five contiguous stereocenters in a multi-cascade reaction, Yimin Hu*, Ying Ouyang, Yuan Qu, Qiong Hu and Hao Yao, Chemical Communications, 2009, 4575-4577.         

19. “Tuned C-H Functionalization to Construct the Skeleton of Aza-Podophyllotoxin/Aza-Conidendrin via Domino Cyclization”, Yimin Hu*, Yuan Qu, Fenghua Wu, Jinghan Gui, Yun Wei, Qiong Hu and Shaowu Wang*, Chemistry-An Asian Journal, 20105, 309-314.         

20. “Efficient Construction of Five-membered Aromatic and Nonaromatic Heterocycles from 1,6-Enynes by a Palladium-Catalyzed Domino Coupling/Cycloisomerization Process”, Tuanjie Meng, Yimin Hu,* and Shaowu Wang*Journal Organic Chemistry, 201075, 582-588.         

21. “Palladium-Catalyzed C-C Coupling/C-H Activation: Formation of Isoindolinone-Fused Heterocyclic Compounds”, Yimin Hu,* Dong Ren, Lidong Zhang, Xiangang Lin, Jing Wan, European Journal Organic Chemistry, 2010, 4454-4459.         

22. “Coupling/Cyclization of 1,6-Enynes with Aryl Halides: an Efficient and General Route for the Synthesis of Functionalized Hexahydroindole and Hexahydrobenzofuran Derivatives”, Tuanjie Meng, Yimin Hu,* Yongjie Sun, Tao Zhu, and Shaowu Wang*Tetrahedron, 20108648-8653.         

23. “A Convenient Domino Synthesis of 4,9-Diphenyl-2,3-dihydro-1H-benzo[f]iso-indole Derivatives”, Yimin Hu,* Xiangang Lin, Tao Zhu, Jing Wan, Yongjie Sun, Quansheng Zhao, Tao Yu, Synthesis, 2010,3467-3473.        

24. "Palladium-Catalyzed Cyclization of Benzyl Halides with Diethyl Diallylmalonate″ Yimin Hu, Jie Zhou, Hongzhen Lian, Chengjian Zhu, Yi Pan*, Synthesis (Issue 8, 1177-1180, 2003).        

25. "Palladium-catalyzed cascade reaction of N-allyl-N-(2-butenyl)-p–toluenesulfon amide with benzyl halides″Yimin Hu, Jie Zhou, Xiangtian Long, Jianlin Han, Chenjian Zhu, Yi Pan*, Tetrahedron Letters (Vol.44, Issue 17, 5009-5010, 2003).        

26. "Palladium-catalyzed cascade reaction of N, N-diallylbenzoylamide with benzyl halides″Yimin Hu, Yu Zhang, Jianlin Han, Chengjian Zhu, Yi Pan* Chinese Chemical Letters (Vol. 14, 771-772, 2003).         

27. "Synthesis and Disproportionation of Mixed Ligand Indium Organometallics Involving Ethyl and β -Diketonate Chelate Ligands″, Yimin Hu, Xiaohua Huang, Zhongwen Ye*, Xiuran Wang, Jiashan Gu, Chinese Journal of Chemistry , (Vol 19, 109-112, 2001). 

         

  会议论(lun)文

1. "Fused multifunctionalized dibenzoselenophenes from tetraynes" Baohua Liu and Yimin Hu*, 4th European Chemistry Congress(Invited Oral Lecture), (May 11-13, 2017, Barcelona, Spain, 2017).        

2. "ONSTRUCTION OF CONDENSED NUCLEUS BY PALLADIUM-CATALYZED DOMINO CYCLIZATION", Lidong Li and Yimin Hu*, The Collaborative Conference on Organic Synthesis (CCOS)Graduate University of Science and Technology (GUST) (Invited Oral Lecture), (March 13-17, Hanoi, Vietnam, 2017)       

3. "Efficient Construction of Fused Heterocycles by Palladium-Catalyzed C-H Activation Domino Reaction″, Qiong Hu, Dong Ren, Lidong Zhang, Tao Zhu, Yongjie Sun and Yimin Hu*The 2010 International Conference on Pure and Applied Chemistry (Oral Presentation), (July 25-30, Mauritius, 2010).        

4. "Disproportionation of Indium Organometallics Involving Ethyl and Chelate Ligands″, Yimin Hu, Xiaohua Huang, Zhongwen Ye*, Xiuran Wang, Baohui Du, The 19th IUPAC International Conference on Organometallic Chemistry, (July 23-28, Shanghai China, PS056, 2000).        

5. "构筑苯(ben)并环化异吲哚骨架的Domino反应研究万静(jing),林(lin)先(xian)刚(gang),姚浩,胡益民*,第(di)六届全(quan)国有机化学会议(yi), P775, 中国, 西安, 2009817-20.        

6. "形成(cheng)吲(yin)哚化合物(wu)及其衍生物(wu)反应中的钯(ba)氧化催化研(yan)究孟团结,胡(hu)益民*,朱(zhu)涛,孙永杰(jie),王绍武*,第六届全国有机化学会(hui)议(yi), P774, 中(zhong)国, 西安, 2009817-20.        

7. "在离(li)子液体(ti)中进(jin)行的电化学支(zhi)持的Heck反应曲(qu)媛, 卢(lu)嘉, 桂敬汉(han), 胡益(yi)民*, 褚道葆*, 第五届全国有机化学会议, P330, 中(zhong)国(guo), 郑州, 2007818-22.        

8. "镍催化的电化学偶联反应卢(lu)嘉, 曲媛, 桂敬汉, 褚道葆(bao)*, 胡(hu)益民*, 第(di)五(wu)届全国(guo)有机化学(xue)会议, P331,中(zhong)国(guo), 郑州(zhou), 2007年(nian)818-22.        

9. "微波在钯催化下的偶联成环反应中的应用胡益(yi)民*, 张(zhang)霞, 曲(qu)媛,吴凤华, 程东,第四届全国有机(ji)化学会议(口(kou)头报告), P96, 中国, 昆明, 200588-11.        

10. "二(er)烯丙基(ji)丙二(er)酸二(er)乙酯与苄基(ji)卤(lu)化物的钯(ba)催化下的成环反应胡益民, 潘毅*,第(di)二届全国有机化学会(hui)议(口头报告), 中国(guo), 杭州, 2001年(nian)85-8.        

11. "有机铟衍(yan)生物(wu)的合(he)成研究胡益(yi)民, 周(zhou)虹屏(ping),叶钟文(wen),王修(xiu)然,第十届全国(guo)金(jin)属有机化学会议, P218, 中国,长沙,199810月(yue)7-11日(ri).        

12. "三乙基铟的合成研究胡益民(min), 黄小华,顾(gu)家山,王修然(ran),叶钟(zhong)文,第(di)十届全国金属(shu)有机化(hua)学(xue)会议, P219, 中国, 长(zhang)沙, 1998107-11日(ri).

         

  专 利                         

         1. 一(yi)种带环外双键二(er)氮杂螺(luo)[4.5]癸烷(wan)衍(yan)生物及其合成方法, 201410293047.1, 授权日期: 2017.1.4

        2. 一种(zhong)芴(wu)酮(tong)衍(yan)生物及(ji)(ji)其制备(bei)以及(ji)(ji)合成芴(wu)酮(tong)的(de)氧化还原方法, 201410725048.9, 授权日期: 2017.1.4       

         3. 一种肉(rou)桂酸酯类衍(yan)生物及其制备方法, 201410728360.3, 授权日期: 2017.1.4                            

         4. 一种安息香(xiang)肟衍生(sheng)物及其制(zhi)备方法, 201410728358.6,  授权日期: 2017.1.11   

         5. 一种(zhong)芳卤衍生物及其(qi)合成方(fang)法(fa),  201410293039.7 , 授权日期: 2017.4.12                            

         6. 一种1,5-二(er)羰基衍(yan)生(sheng)物及其(qi)制备方(fang)法, 201510896115.8, 授权日期: 2017.6.16        

         7. 一种二苯碲醚衍生(sheng)物及其制备方法,  201610070522.8, 授权日期: 2017.10.25                                                                                                

 

 


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