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谢美华

作者:     发布时间: 2020-05-25 点击数:


谢美(mei)华 教授 博士生导师

E-mail: meihuaxie@163.com

实验室: 1111-1112 (礼勤楼)

办公室: 1118 (礼勤楼)

ORCID: 0000-0002-1921-790X



 



所受教育

  1. 学士 (1987年9月-1991年7月) 安徽(hui)师范大学

  2. 硕士 (1991年(nian)9月(yue)-1994年(nian)7月(yue)) 安(an)徽师(shi)范(fan)大学  导师(shi): 沈富仁 教授

  3. 博士(shi) (2000年(nian)3月-2003年(nian)2月) 浙江大学(xue)  导师(shi): 黄(huang)宪 院士(shi)

职称职位

  1. 1994年-现在 安(an)徽(hui)师(shi)范大(da)学 研(yan)究(jiu)(jiu)实习员 助(zhu)理研(yan)究(jiu)(jiu)员 副(fu)研(yan)究(jiu)(jiu)员 教授

  2. 2005年(nian)3月-2006年(nian)3月 香港中文大学 博士(shi)后研(yan)究员

  3. 2004年7月-现(xian)在 硕士生导(dao)师

  4. 2005年 安徽(hui)省高(gao)校中(zhong)青年优秀骨干教师

  5. 2010年 安徽(hui)省(sheng)学(xue)术和技(ji)术带(dai)头人(ren)后备人(ren)选

  6. 2010年4月(yue)-现在 博士生导师(shi)

主持项目

  1. “贫电子炔烃的加成反应及(ji)其在有机合成中的应用研究”,国家自然科学基金,       2013年1月-2016年12月,项(xiang)目负责人(****2004)

  2. “有机金(jin)属试(shi)剂在共轭(e)烯炔类(lei)化合(he)物的立体选择性合(he)成中的应用”,国家自然(ran)科学基金(jin), 2008年1月-2010年12月,项目负(fu)责人(****2001)

  3. “炔基(ji)砜(feng)的碳金属(shu)化(hua)反应及其(qi)在多取代烯烃合成中(zhong)的应用”,国家自然(ran)科学(xue)基(ji)金,2007年1月(yue)(yue)-2009年12月(yue)(yue),项(xiang)目负(fu)责人 (****2001)

  4. 有(you)机金属试剂与(yu)官(guan)能(neng)化炔烃的加(jia)成反应(ying)及其在多取(qu)代烯烃合成中的应(ying)用       安徽省教(jiao)委(wei)基金,2005年1月(yue)-2006年12月(yue),项目负责人(2005KJ129)

  5. 官能化的(de)(de)烯基金(jin)属试(shi)剂的(de)(de)制备及其在多取(qu)代(dai)烯烃(ting)的(de)(de)立体选择性合成中(zhong)的(de)(de)应用       安徽省教委基金(jin),2003年(nian)1月-2004年(nian)12月,项目负(fu)责人

研究领域

  1. 金属有机化学

  2. 有机(ji)合(he)成

讲授课程

  1. 有机(ji)化(hua)学

  2. 高等有机化学

  3. 基础化学(xue)实验

  4. 综合化学实(shi)验

获奖情况

  1. 王绍武,叶钟文,沈富仁(ren), 谢美华(hua) 等(deng)(deng)(deng),“镧(lan)系金属配合(he)物的研究(jiu)-合(he)成、性质与结构”, 1998 年 安徽省高等(deng)(deng)(deng)学(xue)校科技进步(bu)一等(deng)(deng)(deng)奖

  2. 王绍(shao)武,马怀柱,叶钟文,沈富(fu)仁, 谢美华 “稀(xi)土(tu)金属(shu)配合物的研究-合成、性质与结构”, 2000 年 安徽省自然科(ke)学(xue)二等奖

发表论文

  1. Fan Jian, Zhao Yiming, Zhang Jitan, Xie Meihua* and Zhang Yuzhong* “Acid-Controlled Access to β-Sulfenyl Ketones and a,β-Disulfonyl Ketones by Pummerer Reaction of β-Keto Sulfones and Sulfoxides” J. Org. Chem. 2020, 85, 691-701. DOI: 10.1021/acs.joc.9b02766

  2. Zhang Jitan*, Xu Qiaoqiao, Wu Jiaping, Fan Jian and Xie Meihua* “Construction of N-C Axial Chirality through Atroposelective C-H Olefination of N-Arylindoles by Palladium/Amino Acid Cooperative CatalysisOrg. Lett. 2019, 21, 6361-6365. DOI: 10.1021/acs.orglett.9b02243

  3. Zhang Jitan*, Wu Manyi, Fan Jian, Xu Qiaoqiao, Meihua Xie* “Selective C-H Acylation of Indoles at the C4 Position by Pd(II) Catalysis” Chem. Commun. 2019, 55, 8102-8105. DOI: 10.1039/c9cc03893k

  4. Liu Changqing, Wang Bo, Guo Ziyi, Zhang Jitan, Xie Meihua*Metal-Free Cascade Rearrangement/Radical Addition/Oxidative C-H Annulation of Propargyl Alcohols with Sodium Sulfinates: Access to 2-SulfenylindenonesOrg. Chem. Front. 2019, 6, 2796-2800. DOI: 10.1039/C9QO00688E

  5. Chen Jiahui, Jia Jing, Guo Ziyi, Zhang Jitan*, Xie Meihua* NH4I-Promoted N-acylation of amines via the transamidation of DMF and DMA under metal-free conditions Tetrahedron Lett. 2019, 60, 1426-1429. DOI: org/10.1016/j.tetlet.2019.04.040

  6.  Fan Jian, Wang Shengke, Chen Jiahui, Wu Manyi, Zhang Jitan*, Xie Meihua* “Synthesis of 2-Acetyl Trisubstituted Furans via Copper-Mediated Deacylation Cleavage of Unstrained C(sp3)-C(sp2) Bonds” Org. Chem. Front. 2019, 6, 437-441. DOI: 10.1039/c8qo01139g

  7. Zhang Jitan*, Liang Zhenda, Wang Jun, Guo Ziyi, Liu Changqing, Xie Meihua* Metal-Free Synthesis of Functionalized Tetrasubstituted Alkenes by Three-Component Reaction of Alkynes, Iodine and Sodium Sulfinates” ACS Omega 2018, 3, 18002-18015. DOI: 10.1021/acsomega.8b02966

  8. Liu Changqing, Fan Jian, Wu Manyi, Chen Jiahui, Zhao Yiming, Xie Meihua*Metal free mono- and 2,3-bis-sulfenylation of indoles in water with sodium sulfinates as a sulfur source” Chin. J. Chem. 2018, 36, 819-825. DOI: 10.1002/cjoc.****00164

  9. Xie Meihua*, Wang Shengke, Wang Jun, Fang Kuang, Liu Changqing, Zha Chao, Jia Jing “Construction of Substituted Benzenes via Pd-Catalyzed Cross-Coupling/Cyclization Reaction of Vinyl Halides and Terminal Alkynes” J. Org. Chem. 2016, 81, 3329-3334. DOI: 10.1021/acs.joc.6b00308

  10. Wang Shengke, Liu Changqing, Jia Jing, Zha Chao, Xie Meihua*, Zhang Nianrong “Synthesis of sulfonyl-substituted furans via copper-mediated annulation of acetylenic sulfones and activated methylenes” Tetrahedron 2016, 72, 6684-6691. DOI: org/10.1016/j.tet.2016.08.081

  11. Liu Changqing, Zha Chao, Jia Jing, Fan Jian, Liang Zhenda, Yin Zhengchun, Sun Ying, Xie Meihua*Three-component coupling of acetylenic sulfones, Grignard reagents and α, β-unsaturated carbonyls: a convenient synthesis of diallylic alcohols”J. Organomet. Chem., 2016, 825-826, 75-82. DOI: org/10.1016/j.jorganchem.2016.10.026

  12. Xie Meihua*, Wang Jun, Fang Kuang, Wang Shengke, Yan Liqin “Regio- and Stereoselective Synthesis of (E)-β-Halo Alkenyl Ketones/Sulfones via Haloallylation of Alkynyl Ketones/Sulfones” Tetrahedron Lett. 2015, 56, 4388-4391. DOI: 10.1016/j.tetlet.2015.05.098.

  13. Liu Changqing, Zhang Zhannan, Zhang Jitan, Liu Xing, Xie Meihua* “Regioselective Synthesis of Aurone Derivatives via PBu3-Catalyzed Cyclization of 2-AlkynoylphenolsChin. J. Chem., 2014, 32, 1233-1237.

  14. Xie Meihua*, Zhang Jitan, Ning Peng, Zhang Zhannan, Liu Xing, Wang Linbo “Regio- and stereoselective synthesis of highly functionalized vinyl ethers via coiodination of acetylenic ketones” Tetrahedron Lett. 2014, 55, 1065-1067.

  15. Zuo Wansheng, Zhang long, Xie Meihua*, Deng Liang* “Square Planar Nickle(II) Complexes with Halogenated o-Diiminobenzosemiquinonato Ligation: Synthesis, Characterization, and Redox Property” Chin. J. Chem., 2013, 31, 1473-1482.

  16. Fang Kuang, Xie Meihua*, Zhang Zhannan, Ning Peng, Shu Guanying “Nickel-catalyzed cross-coupling reaction of acetylenic sulfones with alkynyl Grignard reagents: a facile method for the preparation of unsymmetrical 1,3-diynes” Tetrahedron Lett. 2013, 54, 3819-3821. DOI: 10.1016/j.tetlet.2013.05.049

  17. Xie Meihua*, Li Ming, Liu Changqing, Zhang Jitan, Feng Chengyou “Facile Regioselective Synthesis of 5-Hydroxy-4,5-dihydroisoxazoles from Acetylenic Ketones” J. Heterocyclic Chem. 2012, 49(6), 1462-1465. DOI 10.1002/jhet.1033

  18. 张继坦,张金花,方旷,束官莹,谢美华*Fe(III)催化的烯丙醇的Friedel-Crafts环化反应(ying)合成多取代(dai)茚有(you)机化学,2012, 32, 1533-1538. DOI 10.6023/cjoc1202271

  19. Xie Meihua*, Feng Chengyou, Zhang Jitan, Liu Changqing, Fang Kuang, Shu Guanying, Zuo Wansheng CuI-Catalyzed tandem carbomagnesiation/carbonyl addition of Grignard reagents with acetylenic ketones: convenient access to tetrasubstituted allylic alcoholsJ. Organomet. Chem., 2011, 696, 3397-3401.

  20. Xie Meihua*, Zhao Xinyang, Lin Gaofeng, Zhang Jinhua “FeCl3·6H2O-Catalyzed bromocyclization to access functionalized dihydropyrans” Synth. Commun. 2011, 41, 1227-1238.

  21. Xie Meihua*, Xie Fadong, Lin Gaofeng, Zhang Jinhua “Convenient synthesis of bis(indolyl)alkanes and bis(pyrrolyl)alkanes by Cu(OTf)2-catalyzed addition of indole and pyrrole to acetylenic sulfone Tetrahedron Lett. 2010, 51, 1213-1215.

  22. Xie Meihua*, Lin Gaofeng, Zhang Jinhua, Li Ming, Feng Chengyou “Regio- and stereoselective synthesis of tetrasubstituted allylic alcohols by three component reaction of acetylenic sulfone, dialkylzinc, and aldehydeJ. Organomet. Chem., 2010, 695(6), 882-886.

  23. Xie Meihua*, Zhang Jinhua, Zhao Xinyang, Lin GaofengAn efficient synthesis of polysubstituted dihydropyrans via iodocyclization reaction of allylic alcoholsChin. J. Chem., 2010, 28(6), 961-966.

  24. Xie Meihua*, Wang Jialiang, Zhang Wei, Wang Shaowu* “Regio- and stereospecific synthesis of vinyl halides via carbozincation of acetylenic sulfones followed by halogenation” J. Organomet. Chem., 2009, 694, 2258-2262.

  25. Xie Meihua*, Gu Xiaoxia, Wang Jialiang, Zhang Jinhua, Lin Gaofeng, Wang Shaowu “Regio- and stereospecific synthesis of polysubstituted alkenes by carbozincation of acetylenic sulfones” Appl. Organomet. Chem. 2009, 23, 258-266.

  26. Xie Meihua*, Sun Ying, Zhang Wei, Gu Xiaoxia, Zhao Xinyang, Xie Fadong, Wang Shaowu “Stereoselective synthesis of allylic amines by one-pot tandem reaction of acetylenic sulfone, Grignard reagent, and N-tosylimine” Synth. Commun. 2008, 38(21), 3785-3796.

  27. Gu Xiaoxia, Xie Meihua*, Zhao Xinyang, Sun Ying, Zhang Wei, Xie Fadong, Wang Shaowu “An efficient synthesis of polysubstituted 1,3-enynes from (E)-β-iodovinyl sulfones and terminal alkynes” Chin. J. Chem., 2008, 26, 1625-1629.

  28. Xie Meihua*, Wang Jialiang, Gu Xiaoxia, Sun Ying, Wang Shaowu* “Highly regio- and stereoselective synthesis of tetrasubstituted olefins by the three-component tandem reaction of allyzinc bromide, acetylenic sulfone, and halohydrocarbon” Org. Lett. 2006, 8(3), 431-434.

  29. Gao, Minli, Tang Yong*, Xie Meihua, Qian Changtao, Xie Zuowei* “Synthesis, structure, and olefin polymerization behavior of constrained-geometry group 4 metallacarboranes incorporating imido-Dicarbollyl ligands” Organometallics 2006, 25, 2578.

  30. Xie Meihua*, Liu Li, Wang Jialiang, Wang Shaowu* “Stereoselective synthesis of vinyl sulfones by carbomagnesiation of acetylenic sulfone in the presence of CuCN” J. Organomet. Chem., 2005, 690, 4058-4062.

  31. Xie Meihua, Huang Xian* “Highly Stereoselective Synthesis of Phenylseleno- and p-Tolylsulfonyl Substituted 1, 3-Dienes from Functionalized Allyl Alcohols” Chin. J. Chem., 2004, 2, 184.

  32. Xie Meihua, Liu Xinyuan, Wang Shaowu*, Liu Li “Synthesis, Structure and Catalytic Activity Comparison of Tris- and Tetracoordinated Lanthanide Amides” Chin. J. Chem. 2004, 22, 678.

  33. Xie Meihua,, Huang Xian* “Crystal Structures of (Z)-1-Phenyl-1-phenylseleno-2-(p- Tolylsulfonyl)ethene and (Z)-1,3-DiPhenyl-3-phenylseleno-2-(p-tolylsulfonyl) -2-propen-1-ol” Chin. J. Struct. Chem. 2004, 23, 543.

  34. Xie Meihua, Huang Xian* “Carbomagnesiation of Acetylenic Sulfones Catalyzed by CuCN and its Application in the Stereoselective Synthesis of Polysubstitited Vinyl Sulfones” Synlett 2003, 4, 477-480.

  35. Xie Meihua, Huang Xian* “Stereoselective Synthesis of Substituted Allyl Selenide by the Reaction of (E)-3-Selanyl Vinylzirconocene Chloride with Aldehydes or Acyl Chlorides” J. Chem. Research 2003, 4, 138.

  36. Xie Meihua, Huang Xian* “Preparation of Selanyl-substituted Conjugated Enynes by Copper-catalyzed Coupling Reaction of (E)-g-Selanyl Vinylzirconocene with Acetylenic Bromide” J. Chem. Research 2003, 9, 584.

  37. Xie Meihua, Wu Luling, Huang Xian* “A Stereoselective Synthesis of Substituted Allyl Alcohol By Three Component Reaction of Actylenic Sulfone, Phenylselenomagnesium Bromide and Ketones” Chinese Chem. Lett. 2003, 14, 887.

  38. Xie Meihua, Wu Luling, Huang Xian* “Stereoselective Synthesis of d -Selanyl Allylic Alcohols by Hydrozirconation of Propargyl Selenides” Chinese Chem. Lett. 2003, 14, 255.

  39. Huang Xian*, Xie Meihua “Michael-aldol Tandem reaction of acetylenic sulfone, Phenylselenomagnesium Bromide and Aldehyde. An Efficient Synthesis of Functionalized Allylic alcohols” Org. Lett. 2002, 4, 1331-1334.

  40. Huang Xian*, Xie Meihua "Highly Stereoselective Three-component Reactions of Phenylselenomagnesium Bromide, Acetylenic Sulfones and Saturated Aldehydes/Ketones or αβ -Unsaturated Enals or Enones" .J. Org. Chem., 2002, 67, 8895-8900.

  41. Xie Meihua, Hao, Xueshi, Ma, Huaizhu “Crystal Structure of Bis{1-(2-methoxyethyl) indenyl}dysprosium Chloride” Chinese J. Struct. Chem. 2000, 19, 253-258.

  42. Xie Meihua, Qian, Changtao*, Gao, Lijuan, Sun, Jie “Synthesis and Structure of Barium Complex Containing 2,2,6,6-tetramethyl-3,5-heptanedionate and 1, 10-Phenanthroline Ligands” Chinese J. Struct. Chem. 200019, 419-422.

  43. Ma Yun, Qian Changtao.*, Xie Meihua, Sun Jie “Lanthanide Chloride Catalyzed Imino Diels-Alder Reaction. One-Pot Synthesis of Pyrano[3,2-c]- and Furo[3,2-c]quinolines” J. Org. Chem. 1999, 64, 6462.

  44. Shen Furen*, Xie Meihua, Hu Jiping, Wang Shaowu “Synthesis and Structural study of Cyclopentadienyl Lanthanide Derivatives Containing the 2-Naphthoyltrifluoroacetonato Ligand” Polyhedron 1996, 15, 1151.

  45. Shen Furen*, Hu Jiping, Xie Meihua, Wang Shaowu “Synthesis and Structural investigation of Lanthanide Organometallics involving cyclopentadienyl and 2-naphthoyltrifluoroacetonato chelate ligands” J. Organomet. Chem. 1995, 484, C6-C9.

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