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周双六

作者: 周双六     发布时间: 2019-05-29 点击数:

 

  

 

 

周双六 教授 博士(shi)生导师

E-mail: slzhou@littlemommynest.com

电话: 0553-3937138

ORCID:


      

所受教育:

·  学(xue)士 (1991-1995 安徽工程大(da)学

·  硕士(shi) (2000-2003 安徽师范大学

·  博(bo)士 (2004-2007 安徽师范(fan)大学


职(zhi)称职(zhi)位(wei):

·  2003年-现在    安(an)徽师范大学讲(jiang)师,副教授,教授(2012年(nian))

·  2007年-2009  台湾中(zhong)兴(xing)大学化学系(xi)博士后研究员

·  200811月(yue)-现(xian)在    安徽师范大学硕士生导师

·  201712月(yue)-现在    安(an)徽师范(fan)大学博(bo)士生导师


主持(chi)项目(mu):

   1. 含氮、氧原(yuan)子侧链吡咯基(ji)(ji)多齿配(pei)体稀土金属配(pei)合物的(de)合成(cheng)及其反应性研究,国家自然科学(xue)基(ji)(ji)金(21672004)2017-2020,项目主持人。

   2. 新型手(shou)性稀(xi)土金属胺基配合(he)物的合(he)成及其催化碳-磷键(jian)选择性形成反(fan)应研究,国家自然(ran)科学基金(21372009)2014-2017,项目主持人,已结题

   3. 手性稀土(tu)金(jin)属配合物催化芳香(xiang)基(ji)(ji)(或杂芳香(xiang)基(ji)(ji))铝试剂对醛酮的(de)不对称加成反应研究,国家自(zi)然科(ke)学基(ji)(ji)金(jin)(21172003)2012-2015,项目(mu)主持人,已结题。

   4. 单磺酰(xian)基(ji)联萘酚基(ji)锌镁铝(lv)金(jin)属配(pei)合物催化丙(bing)交酯开环(huan)聚合反应研(yan)究,安徽省自然科(ke)学基(ji)金(jin)(11040606M36)2011-2013,项(xiang)目主持人,已结(jie)题。

   5. 外消旋稀土金属有机(ji)配合(he)物的控制性合(he)成及其催化烯(xi)烃可控聚合(he)研究,国(guo)家自然科学基(ji)金(21802001)2009-2011,项(xiang)目(mu)主持人,已(yi)结题。

   6. 氮(dan)原子配位促进(jin)稀土(tu)金属(shu)-氮键(jian)均裂反应研究(jiu),安徽省高校青年(nian)教师资助计(ji)划(2004jq120),项目(mu)主持人,已结题。


研究领域:

   1. 金属有机化学(xue)

   2. 不对称(cheng)催化合成(cheng)


讲授课程:

   1. 化(hua)工基础

   2. 应用有机合成

   3. 化学文献检(jian)索(suo)与利用

   4. 工程(cheng)制图

   5. 应化专业(ye)实验


代表性论文:


28. Xiuli Zhang, Shuangliu Zhou,* Donghan Wang, Lijun Zhang, Yun Wei, Xiancui Zhu, Peng Cui, Gen Luo,* Shaowu Wang*, Syntheses of Rare-Earth Metal Alkyl Complexes Bearing a Dianionic a-Iminopyridyl Ligand and Their Catalytic Activities toward Polymerization of 2-Vinylpyridine, Organometallics 2021, 40, 3462-3471.

27. Weiming Sheng, Xiaolong Xu, Shuangliu Zhou,* Xiuli Zhang, Zeming Huang, Jun Du, Lijun Zhang, Yun Wei, Xiancui Zhu, Peng Cui, Shaowu Wang,* Synthesis and Reactivity of NNNNN-Pincer Multidentate Pyrrolyl Rare-Earth-Metal Amido-Chloride or Dialkyl Complexes, Organometallics 2020, 39, 4525-4534.

26. Xiuli Zhang, Shuangliu Zhou,* Xiaofei Fang, Lijun Zhang, Guide Tao, Yun Wei, Xiancui Zhu, Peng Cui, Shaowu Wang.* Syntheses of Dianionic a-Iminopyridine Rare-earth Metal Complexes and Their Catalytic Acitivities toward Dehydrogenative Coupling of Amines with Hydrosilanes”, Inorg. Chem. 2020, 59, 9683-9692.

25. Wei Wang, Xiaojia Wang, Shuangliu Zhou,* Xiaolong Xu, Jun Du, Lijun Zhang, Xiaolong Mu, Yun Wei, Xiancui Zhu, and Shaowu Wang.* “Syntheses, Structures, and Catalytic Activities of the Anionic Heterobimetallic Rare-Earth Metal Complexes Supported by Pyrrolyl-Substituted 1,2-Diimino Ligands”, Inorg. Chem. 2018, 57, 10390-10400.

24. Hong Fang, Zhiyong Yang, Lijun Zhang, Wei Wang, Yimei Li, Xiaolong Xu, and Shuangliu Zhou.* “Transmetal-Catalyzed Enantioselective Cross-Coupling Reaction of Racemic Secondary Benzylic Bromides with Organoaluminum Reagents”, Org. Lett. 2016, 18, 6022-6025.

23. Shuangliu Zhou*, Zhiyong Yang, Xu Chen, Yimei Li, Lijun Zhang, Hong Fang, Wei Wang, Xiancui Zhu, Shaowu Wang*, “Copper-Catalyzed Electrophilic Amination of Organoaluminum Nucleophiles with O-Benzoyl Hydroxylamines”, J. Org. Chem. 2015, 80, 6323-6228.

22. Lijun Zhang,* Bing Tu, Min Ge, Yimei Li, Liangyu Chen, Wei Wang, and Shuangliu Zhou*, “Asymmetric Addition of Pyridyl Aluminum Reagents to Aldehydes Catalyzed by a Titanium(IV) Catalytic System of (R)-H8-BINOLate”, J. Org. Chem. 2015, 80, 8307-8313.

21.  Hui Miao, Fenhua Wang, Shuangliu Zhou,* Guangchao Zhang, Yang Li, "Palladium-catalyzed Hiyama coupling reaction of arylsulfonyl hydrazides under oxygen", Org. Biomol. Chem., 2015, 13, 4647-4651.

20.  Liping Guo, Xiancui Zhu, Guangchao Zhang, Yun Wei, Lixin Ning, Shuangliu Zhou,* Zhijun Feng, Shaowu Wang,* Xiaolong Mu, Jun Chen, “Synthesis and Characterization of Organo-Rare-Earth Metal Monoalkyl Complexes Supported by Carbon σ-Bonded Indolyl Ligands: High Specific Isoprene 1,4-Cis Polymerization Catalysts”, Inorg. Chem. 2015, 54, 5725-5731.

19. Yun Wei, Shaowu Wang,* Shuangliu Zhou,* Zhijun Feng, Liping Guo, Xiancui Zhu, Xiaolong Mu, Fangshi Yao, “Aluminum Alkyl Complexes Supported by Bidentate N,N Ligands: Synthesis, Structure, and Catalytic Activity for Guanylation of Amines”, Organometallics 2015, 34, 1882-1889.

18. Qingbing Yuan, Shuangliu Zhou,* Xiancui Zhu, Yun Wei, Shaowu Wang,* Xiaolong Mu, Fangshi Yao, Guangchao Zhang and Zheng Chen, "Heterometallic rare-earth metal complexes with imino-functionalized 8-hydroxyquinolyl ligands: synthesis, characterization and catalytic activity towards hydrophosphinylation of trans-β-nitroalkene, New J. Chem., 2015, 39, 7626-7632

17. Xu Chen, Lingmin Zhou, Yimei Li, Tao Xie, Shuangliu Zhou*, “Synthesis of Heteroaryl Compounds through Cross-Coupling Reaction of Aryl Bromides or Benzyl Halides with Thienyl and Pyridyl Aluminum Reagents”, J. Org. Chem. 2014, 79, 230-239.

16. Liping Guo, Xiancui Zhu, Shuangliu Zhou,* Xiaolong Mu, Yun Wei, Shaowu Wang,* Zhijun Feng, Guangchao Zhang, Baojia Deng, "Rare-earth alkyl complexes supported by formamidinate ligands: synthesis, structure, and catalytic activity for isoprene polymerization", Dalton Trans., 2014, 43, 6842-6847.

15. Shuangliu Zhou,* Zhangshuan Wu, Lingmin Zhou, Shaowu Wang,* Lijun Zhang, Xiancui Zhu, Yun Wei, Jinhua Zhai, and Jie Wu, Controlled Synthesis of Racemic Indenyl Rare-Earth Metal Complexes via the Cooperation between the Intramolecular Coordination of Donor Atoms and a Bridge, Inorg. Chem. 2013, 52, 6417−6426.

14. Qinghai Li, Shuangliu Zhou,* Shaowu Wang,* Xiancui Zhu, Lijun Zhang, Zhijun Feng, Liping Guo, Fenhua Wang and Yun Wei, Dehydrogenation of secondary amines: synthesis, and characterization of rare-earth metal complexes incorporating imino- or amido-functionalized pyrrolyl ligands, Dalton Trans. 2013, 42, 2861-2869.

13. Shuangliu Zhou, Zhangshuan Wu, Jiewei Rong, Shaowu Wang,* Gaosheng Yang, Xiancui Zhu, Lijun Zhang, Highly Efficient Hydrophosphonylation of Aldehydes and Unactivated Ketones Catalyzed by Methylene-Linked Pyrrolyl Rare Earth Metal Amido Complexes, Chem. Eur. J. 2012, 18, 2653-2659.

12. Shuangliu Zhou, Hengyu Wang, Jian Ping, Shaowu Wang,* Lijun Zhang,* Xiancui Zhu, Yun Wei, Fenhua Wang, Zhijun Feng, Xiaoxia Gu, Song Yang, and Hui Miao, Synthesis, Characterization of Organolanthanide Complexes with Calix[4]-pyrrolyl Ligand and Their Catalytic Activities towards Hydrophosphonylation of Aldehydes and Unactivated Ketones,  Organometallics 2012, 31, 1696-1702.

11. Shuangliu Zhou,* Yongyao Jiang, Tao Xie, Zhanshuan Wu, Linmin Zhou, Wenjing Xu, Lijun Zhang, Shaowu Wang*, Synthesis, Structure of Zinc Complexes Containing Sulfonylated Binaphtholate Ligands and Their Catalytic Activities towards Ring-Opening Polymerization of Lactide and e-Caprolactone, Chin. J. Chem. 2012, 30, 2176-2182.

10. Shuangliu Zhou, Chengwei Yin, Hui Wang, Xiancui Zhu, Gaosheng Yang, Shaowu Wang*, Synthesis, characterization, and catalytic activities of rare-earth metal complexes with iminopyrrolyl ligands, Inorg. Chem. Commun. 2011, 14, 1194-1120.

9. Shuangliu Zhou, Shihong Wu, Hong Zhu, Shaowu Wang,* Xiancui Zhu, Lijun Zhang, Gaosheng Yang, Daohui Cui, Hengyu Wang, Synthesis, structure and catalytic activity of alkali metal-free bent-sandwiched lanthanide amido complexes with calix[4]-pyrrolyl ligands, Dalton Trans. 2011, 40, 9447-9453.

8. Shuangliu Zhou, Chi-Ren Chen, Han-Mou Gau*, Highly Enantioselective 3-Furylation of Ketones Using (3-Furyl)titanium Nucleophile, Org. Lett. 2010, 12, 48-51.

7. Chao Liu, Shuangliu Zhou,* Shaowu Wang,* Lijun Zhang, Gaosheng Yang, Rare earth metal bis(trimethylsilyl)amido complexes bearing pyrrolyl-methylamide ligand. Synthesis, structure, and catalytic activity towards guanylation of amines, Dalton Trans. 2010, 39, 8994-8999.

6. Shuangliu Zhou, Kuo-Hui Wu, Chien-An Chen, Han-Mou Gau,* Highly Enantioselective Arylation of Aldehydes and Ketones Using AlArEt2(THF) as Aryl Sources, J. Org. Chem. 2009, 74, 3500-3505.

5. Shuangliu Zhou, Da-Wei Chuang, Shih-Ju Chang, Han-Mou Gau,* Synthesis, Characterization, and Structures of Arylaluminum Reagents and Asymmetric Arylation of Aldehydes Catalyzed by a Titanium Complex of N-Sulfonylated Amino Alcohol, Tetrahedron: Asymmetry 2009, 20, 1407-1412.

4. Shuangliu Zhou, Shaowu Wang,* Gaosheng Yang, Qinghai Li, Lijun Zhang, Zijian Yao, Zhangkai Zhou, and Haibin Song, Synthesis, Structure and Diverse Catalytic Activities of Ethylenebis(indenyl)lanthanide(III) Amides on the N-H, C-H Addition to Carbodiimides and e-Caprolactone Polymerization, Organometallics 2007, 26, 3755-3761.

3. Shuangliu Zhou, Shaowu Wang,* Enhong Sheng, Lijun Zhang, Zeyan Yu, Xiaobing Xi, Guodong Chen, Wei Luo, and Yan Li, Synthesis, Characterization and Catalytic Activity of Some Neodymium(III) and Ytterbium(II) and Europium(II) Complexes With Pyrrolidinyl- and Piperidinyl-Functionalized Indenyl Ligands, Eur. J. Inorg. Chem. 2007, 1519-1528.

2. Shaowu Wang,* Shuangliu Zhou, Enhong Sheng, Meihua Xie, Kehua Zhang, Lin Cheng, Yan Feng, Lili Mao, and Zixiang Huang, Homolysis of the Eu-N Bond. “Synthesis, Structural Characterization, and Catalytic Activity of Novel Europium(II) Complexes, Organometallics 2003, 22, 3546-3552.

1. Shuangliu Zhou, Shaowu Wang,* Gaosheng Yang, Xinyuan Liu, Enhong Sheng, Kehua Zhang, Lin Cheng, Zixiang Huang, Synthesis, structure, and catalytic activity of tetracoordinate lanthanide amides [(Me3Si)2N]3Ln(m-Cl)Li(THF)3 (Ln = Nd, Sm, Eu), Polyhedron 2003, 22, 1019-1024.



会议论文及报告

1. 周双六,“有(you)机(ji)(ji)铝试剂在有(you)机(ji)(ji)合成(cheng)中的应用”,第十四届(jie)江淮有(you)机(ji)(ji)论坛。201611月,徐州,报(bao)告。

2. Hong Fang, Xiaolong Xu, Yangyang Jiang, Xiaojia Wang, Shuangliu Zhou*, “Organoaluminum Reagents’ Application on Asymmetric Cross-coupling Reaction”. 第九(jiu)届(jie)全国金属(shu)有机(ji)化(hua)学(xue)(xue)学(xue)(xue)术(shu)会议(yi)。20158月,兰州,墙报。

3. 姜永要,周双六*,周(zhou)凌敏,吴章栓,王绍武*,“磺酰(xian)基取代联萘酚(fen)锌配(pei)合(he)物的合(he)成、结构及(ji)其催化(hua)性质”,第(di)七届(jie)全国有(you)机化(hua)学(xue)学(xue)术(shu)讨论会(hui)。201111月,南(nan)京,墙报。

4. 吴章栓,周双六*,周凌敏,姜永要,王绍武*,“稀土(tu)胺(an)基(ji)化(hua)合(he)物催化(hua)a,b-不饱(bao)和羰(tang)基化合(he)物的氢膦(lin)化反应”,第七(qi)届全国有机化学(xue)学(xue)术(shu)讨(tao)论会(hui)。201111月(yue),南京,墙报。

5. Shuangliu Zhou and Han-Mou Gau*, “Application of the Aluminum Reagents in Enantioselective Arylation of Aldehydes”, 第五(wu)届海(hai)峡两岸生物无机(ji)与材料(liao)研(yan)讨会(hui)。20087月,台南,墙报。

 

 


 



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