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倪祁健

作者: 倪祁健     发布时间: 2019-10-21 点击数:

倪祁健博士 (副教授,硕士生导师)

办(ban)公室:花(hua)津校(xiao)区爱游戏app礼勤楼1116

实验室:花(hua)津校区(qu)爱游戏(xi)app礼勤楼1123-1124

Email:qijianni@littlemommynest.com


教育经历

  • 2004.09-2008.07安徽师(shi)范大学(xue)(xue) 理学(xue)(xue)学(xue)(xue)士(导师(shi): 罗时忠(zhong))

  • 2008.09-2011.07大连理(li)工大学 工学硕士(导师: 刘春)

  • 2011.09-2015.07德国亚琛工业大学 理学博士(导师: Dieter Enders)


工作经历

  • 2015.10-2017.10新加坡国立大(da)学(xue) 博士后(合(he)作导师: 赵宇)

  • 2017.10 至今 安徽师范大学(xue) 爱(ai)游(you)戏app


主持项目

  • 2021.1-2023.12,国家自然科学青(qing)年基金“不(bu)对(dui)称有机(ji)小分(fen)子催(cui)化/去芳(fang)构化策略构建(jian)苯并含氮杂环类(lei)化合物”(22001010),项目(mu)负责(ze)人

  • 2019.7-2021.6 安徽省自然科学(xue)青年基(ji)金“不对称脱羧环化构(gou)建中环含氮杂环化合物”(1908085QB55),项(xiang)目负责人

  • 2018年安(an)徽省(sheng)平台引才资助经费,项目负责人

  • 安徽师范大学博士科(ke)研启(qi)动基金,项目(mu)负责人


研究领域

  • 不对称(cheng)过渡金(jin)属催化(hua)

  • 有机小(xiao)分(fen)子催化


课题组成员

  • 在读硕士(shi)生:

    19级(朱智铭(ming)、许方(fang)方(fang)、范彦君)

    20级(张莅(li)蓉、姜旭华、秦唯)

    21级(张璇、张晗(han)、邵(shao)雪城(cheng))

  • 已(yi)毕业(ye)硕士生: 王旭(xu)阳(南开大学攻读博士)、曾(ceng)达、许(xu)磊

  • 本科(ke)生:

    16级大学生(sheng)创新实验团队(dui)(顾(gu)孟杰、荚(jia)瑞、沈月;唐伟、张莅蓉、张利(li)沙(sha))

    17级大学(xue)生创新训练项目(张(zhang)旭) 

    18级大学(xue)生创新训练项(xiang)目(赵远,周(zhou)欢)


已发表论文

19) Qijian Ni*, Xuyang Wang, Da Zeng, Qianling Wu, Xiaoxiao Song*.Chiral Phosphoric Acid Catalyzed Desymmetrization of Cyclopentendiones via Friedel–Crafts Conjugate Addition of Indolizines,Org.Lett.DOI:10.1021/acs.orglett.1c03780.

18) Qijian Ni*, Xuyang Wang, Da Zeng, Qianling Wu, Xiaoxiao Song*.Organocatalytic Asymmetric Synthesis of Aza-Spirooxindoles via Michael/Friedel-Crafts Cascade Reaction of 1,3-Nitroenynes and 3-Pyrrolyloxindoles,Org.Lett.2021,23,2273-2278.

17) Qijian Ni, Xiaoxiao Song, Chin Wen Png, Yongliang Zhang*, Yu Zhao*. Access to Substituted Cyclobutenes by Tandem [3,3]-Sigmatropic Rearrangement/[2+2] Cycloaddition of Dipropargylphosphonates under Ag/Co Relay Catalysis,Chem. Sci.,2020,11,12329-12335.

16) Xiaoxiao Song*, Lei Xu,Qijian Ni*. Highly diastereoselective synthesis of 3-methylenetetrahydropyrans by palladium catalyzed oxa-[4 + 2] cycloaddition of 2-alkenylbenzothiazoles,Org. Biomol. Chem.2020,18, 6617-6621.

15) Qijian Ni*, Xuyang Wang, Fangfang Xu, Xiaoyun Chen, Xiaoxiao Song*. Organocatalytic asymmetric [4+2] cyclization of 2-benzothiazolimines with azlactones: access to chiral benzothiazolopyrimidine derivatives,Chem. Commun.2020,56,3155-3158.

14) Xiaoxiao Song*, Mengjie Gu, Xiaoyun Chen, Lei Xu,Qijian Ni*. Highly Stereoselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Epoxides and N-Benzothiazolimine,Asian J. Org. Chem.2019,8, 2180-2183.

13) Jiayu Liao,Qijian Ni, Yu Zhao*. Catalyst-Enabled Scaffold Diversity: Highly Chemo- and Stereoselective Synthesis of Tricyclic Ketals and Triarylmethanes,Org. Lett.2017,19, 4074-4077.

12) Tao Shu,Qijian Ni, Xiaoxiao Song, Kun Zhao, Tianyu Wu, Rakesh Puttreddy, Kari Rissanen, Dieter Enders*. Asymmetric synthesis of cyclopentanes bearing four contiguous stereocenters via an NHC-catalyzed Michael/Michael/esterification domino reaction,Chem. Commun.2016,52, 2609-2611.

11) Qijian Ni, Jiawen Xiong, Xiaoxiao Song, Gerhard Raabe, Dieter Enders*. NHC-Catalyzed Activation of α,β-Unsaturated N-Acyltriazoles: An Easy Access to Dihydropyranones,Chem. Commun.2015,51, 14628-14631.

10) Qijian Ni, Jiawen Xiong, Xiaoxiao Song, Gerhard Raabe, Dieter Enders*. NHC-Catalyzed Enantioselective Annulation of Benzothiazolyl Ethyl Acetates with 2-Bromoenals,Synlett2015,26, 1465-1469.

9) Qijian Ni, Xiaoxiao Song, Jiawen Xiong, Gerhard Raabe, Dieter Enders*. Regio- and stereoselective synthesis of benzothiazolo-pyrimidinones via an NHC-catalyzed Mannich/lactamization domino reaction,Chem. Commun.2015,51, 1263-1266.

8) Lei Wang,Qijian Ni, Marcus Blümel, Tao Shu, Gerhard Raabe, Dieter Enders*. NHC-Catalyzed Asymmetric Synthesis of Functionalized Succinimides from Enals and α-Ketoamides,Chem. Eur. J.2015,21, 8033-8037.

7) Qijian Ni, Xiaoxiao Song, Gerhard Raabe, Dieter Enders*. N-Heterocyclic Carbene-Catalyzed Enantioselective Annulation of Indolin-3-ones with Bromoenals,Chem. Asian J.2014,9, 1535-1538.

6) Xiaofei Zeng,Qijian Ni, Gerhard Raabe, Dieter Enders*. A Branched Domino Reaction: Asymmetric Organocatalytic Two-Component Four-Step Synthesis of Polyfunctionalized Cyclohexene Derivatives,Angew. Chem. Int. Ed.2013,52, 2977-2980.

5) Qijian Ni, Huan Zhang, André Grossmann, Charles C. J. Loh, Carina Merkens, Dieter Enders*. Asymmetric Synthesis of Pyrroloindolones by N-Heterocyclic Carbene Catalyzed [2+3] Annulation of α-Chloroaldehydes with Nitrovinylindoles,Angew. Chem. Int. Ed.2013,52, 13562-13566. (highlighted in SYNFACTS 2014, 212)

4) Chun Liu*,Qijian Ni, Fanying Bao, Jieshan Qiu. A simple and efficient protocol for the palladium-catalyzed ligand-free Suzuki reaction at room temperature in aqueous DMF,Green Chem.2011,13, 1260-1266.

3) Chun Liu*,Qijian Ni, Jieshan Qiu*. Very Fast, Ligand-Free and Aerobic Protocol for the Synthesis of 4-Aryl-Substituted Triphenylamine Derivatives,Eur. J. Org. Chem.2011, 3009-3015.

2) Chun Liu*,Qijian Ni, Pingping Hu, Jieshan Qiu. Oxygen-promoted PdCl2-catalyzed ligand-free Suzuki reaction in aqueous media,Org. Biomol. Chem.2011,9, 1054-1060.

1) 刘春*,倪祁健, 胡萍萍, 袁浩,金子林。水溶性亚胺配体/钯催化的室温Suzuki反应,催化学报,2010,31,1277-1280.


链接

新加坡国立(li)大学教授

德国(guo)亚琛工业大学教授(shou)


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